摘要: |
合成了植酸保护的纳米金,其具有较强的疏水性和表面增强拉曼散射(SERS)活性.利用小型拉曼光谱仪和分子光谱的指纹信息特征,建立可同时分析水中多种多环芳烃的SERS分析方法.多环芳烃检出限如下:蒽为100 μg/L,荧蒽为100 μg/L,芘达到10 μg/L 和苯并芘可达1 μg/L. |
关键词: 表面增强拉曼散射光谱 植酸修饰纳米金 蒽 荧蒽 芘 苯并芘 同时检测 |
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基金项目:国家自然科学基金项目(21475088,21507087);上海师范大学大学生创新实验项目(A-9103-15-035100);上海市扬帆计划(15YF1409000);上海市教委化学高原(I)学科 |
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Surface enhanced Raman scattering technique for simultaneous detection of four trace polycyclic aromatic hydrocarbons |
FU Shuyue, ZHANG Qi, CHEN Lu, GUO Xiaoyu, YING Ye, WU Yiping, WEN Ying, YANG Haifeng
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The Education Ministry Key Lab of Resource Chemistry,College of Life and Environmental Sciences,Shanghai Normal University
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Abstract: |
Phytic acid modified Au (IP6@Au) nanoparticles with high surface enhanced Raman scattering (SERS) activity as well as hydrophobicity were synthesized.Based on IP6@Au and the molecular fingerprint information,we developed a SERS-based method for simultaneous detection of four polycyclic aromatic hydrocarbon species in river water by using a portable Raman system.The limit of detection for anthracene,fluoranthene,pyrene and benzopyrene were 100,100,10 and 1 μg/L,respectively. |
Key words: surface enhanced Raman scattering IP6@Au anthracene fluoranthene benzopyrene pyrene simultaneous detection |