摘要: |
有机聚合物手性催化剂是一种将手性催化剂固载在成型聚合物上或者直接共聚成聚合物所形成的高聚物催化剂.由于其制备简易、性质多样和容易回收再利用等特点受到了广泛的关注,成为了国内外科学家的研究热点.简要的总结了由有机小分子催化剂和金属催化剂所形成聚合物手性催化剂,并对该领域的发展前景作出了展望,为其进一步研究提供了参考. |
关键词: 聚合物 手性催化剂 固载 回收利用 |
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基金项目:上海师范大学项目(SK201329);上海市教委基金(S30406);大学生创新活动计划基金 |
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Recent progress of organic polymer supported chiral catalysts |
XU Yuanyuan, CHENG Tanyu, WEI Xing, LI Xiaomin, CHEN Qianyun, LIU Guohua
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College of Life and Environment Sciences, Shanghai Normal University
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Abstract: |
Organic polymer-supported chiral catalysts are usually prepared by copolymerizing chiral catalysts or immobilized them on organic polymers They have been attracted due to their excellent properties,such as easy preparation,various characters and convenient recycle.This review introduced the organic polymer-supported chiral organocatalysts and metal catalysts,and look forward to the future development and prospects of this field. |
Key words: polymer chiral catalyst immobilization recycle |