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丝网印刷法制备纸质SERS基底及其性能研究
王昆, 余嘉雯, 严佳, 杨欣婕, 肖桂娜
上海师范大学 数理学院, 上海 200234
摘要:
以绘画纸、白卡纸和坐标纸为衬底,采用丝网印刷银油墨,制备了高效的表面增强拉曼散射(SERS)基底,结果表明:银薄膜/绘画纸的SERS活性最佳,其次是银薄膜/白卡纸和银薄膜/坐标纸,对结晶紫的最低检测限分别为10-8,10-7和10-7 mol·L-1.此外,在同一银薄膜/绘画纸表面随机选取10个不同位置,在特征峰913,1 179和1 620 cm-1处,强度的相对标准偏差值分别为13.2%,12.5%和10.6%,增强因子达到2.87×105,表明该基底具有较好的均匀性.
关键词:  表面增强拉曼散射(SERS)  丝网印刷  银薄膜    结晶紫
DOI:10.3969/J.ISSN.1000-5137.2021.04.002
分类号:O647
基金项目:上海市自然科学基金(19ZR1437700);上海师范大学一般项目(SK202138)
Preparation of paper-based SERS substrates by screen printing and property research
WANG Kun, YU Jiawen, YAN Jia, YANG Xinjie, XIAO Guina
College of Mathematics and Sciences, Shanghai Normal University, Shanghai 200234, China
Abstract:
An efficient surface enhanced Raman scattering(SERS)substrate was prepared by screen printing silver ink on drawing paper, white card paper and coordinate paper. The results showed that silver film/drawing paper represented the best SERS activity, followed by silver film/white card paper and silver film/coordinate paper. The minimum detection limits for crystal violet were 10-8, 10-7 and 10-7 mol·L-1, respectively. In addition, ten different positions were randomly selected on the same silver film/drawing paper surface, and the relative standard deviation values of the peak intensitiesat 913, 1 179 and 1 620 cm-1 were 13.2%, 12.5% and 10.6%, respectively, which indicated outstanding uniformity.
Key words:  surface enhanced Raman scattering(SERS)  screen printing  silver film  paper  crystal violet