摘要: |
以绘画纸、白卡纸和坐标纸为衬底,采用丝网印刷银油墨,制备了高效的表面增强拉曼散射(SERS)基底,结果表明:银薄膜/绘画纸的SERS活性最佳,其次是银薄膜/白卡纸和银薄膜/坐标纸,对结晶紫的最低检测限分别为10-8,10-7和10-7 mol·L-1.此外,在同一银薄膜/绘画纸表面随机选取10个不同位置,在特征峰913,1 179和1 620 cm-1处,强度的相对标准偏差值分别为13.2%,12.5%和10.6%,增强因子达到2.87×105,表明该基底具有较好的均匀性. |
关键词: 表面增强拉曼散射(SERS) 丝网印刷 银薄膜 纸 结晶紫 |
DOI:10.3969/J.ISSN.1000-5137.2021.04.002 |
分类号:O647 |
基金项目:上海市自然科学基金(19ZR1437700);上海师范大学一般项目(SK202138) |
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Preparation of paper-based SERS substrates by screen printing and property research |
WANG Kun, YU Jiawen, YAN Jia, YANG Xinjie, XIAO Guina
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College of Mathematics and Sciences, Shanghai Normal University, Shanghai 200234, China
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Abstract: |
An efficient surface enhanced Raman scattering(SERS)substrate was prepared by screen printing silver ink on drawing paper, white card paper and coordinate paper. The results showed that silver film/drawing paper represented the best SERS activity, followed by silver film/white card paper and silver film/coordinate paper. The minimum detection limits for crystal violet were 10-8, 10-7 and 10-7 mol·L-1, respectively. In addition, ten different positions were randomly selected on the same silver film/drawing paper surface, and the relative standard deviation values of the peak intensitiesat 913, 1 179 and 1 620 cm-1 were 13.2%, 12.5% and 10.6%, respectively, which indicated outstanding uniformity. |
Key words: surface enhanced Raman scattering(SERS) screen printing silver film paper crystal violet |