| 摘要: |
| 通过层层自组装技术，构建植酸锆/普鲁士蓝（Zr-IP6/PB）多层结构膜.基于普鲁士蓝（PB）对双氧水（H2O2）有很高的电催化性能，加之5层植酸锆/普鲁士蓝膜多孔结构有利于传质过程，该H2O2传感器具有高灵敏度和高选择性.实验结果显示：修饰电极对H2O2响应的物质的量浓度范围为2.00×10-5~1.76×10-3 mol·L-1，线性相关系数R=0.998 9. |
| 关键词: 植酸锆 普鲁士蓝(PB) 双氧水(H2O2)传感器 自组装 |
| DOI：10.3969/J.ISSN.1000-5137.2019.04.012 |
| 分类号:O647.3 |
| 基金项目:国家自然科学基金（21475088） |
|
| Zirconium phytate/Prussian blue composite membrane and its electrocatalytic behavior |
|
HUANG Xinhua, DONG Jie, GUO Xiaoyu, WEN Ying, YANG Haifeng
|
|
College of Chemistry and Materials Science, Shanghai Normal University, Shanghai 200234, China
|
| Abstract: |
| The zirconium phytate/Prussian blue(Zr-IP6/PB) multilayer structure film was constructed by layer-by-layer self-assembly technology.Since Prussian blue(PB) has high electrocatalytic performance for H2O2,and the 5-layer Zr-IP6/PB membrane with porous structure is beneficial to the mass transfer process,the as-prepared hydrogen peroxide sensor shows high sensitivity and selectivity.The result showed that the linear concentration response range of such modified electrode on H2O2 is from 2.00×10-5 to 1.76×10-3 mol·L-1,and the linear correlation coefficient (R) is 0.998 9. |
| Key words: zirconium phytate Prussian blue(PB) H2O2 sensor self-assembly |
